Naples is a village in Ontario County, New York, United States. The population was 1,041 at the 2010 census. It is a part of the Town of Naples, known as an important grape-growing region. The village, one of the first places populated by pioneers, was first settled around 1790. The village was incorporated in 1894. The Village of Naples has had voteā¦Naples is a village in Ontario County, New York, United States. The population was 1,041 at the 2010 census. It is a part of the Town of Naples, known as an important grape-growing region. The village, one of the first places populated by pioneers, was first settled around 1790. The village was incorporated in 1894. The Village of Naples has had votes in 1994, 2001 and June 2005 respectively in reference to dissolving the village into the Town of Naples, with all three results going against the proposal. The Naples Branch of the Lehigh Valley Railroad terminated in the village.